New derivatization method for determination of 3-chloro-4(dichloromethyl)-5-hydroxy-2(5H)-furanone in water

An extremely potent mutagen, 3-chloro-4(dichloromethyl)-5-hydroxy-2(5H)-furanone (MX) is commonly present in chlorinated drinking water. Due to its high mutagenic activity and according to World Health Organization guidelines its concentration should be controlled in drinking waters. Determination of MX is difficult due to ppt levels at which the compound usually exists in drinking waters. Derivatization of MX with 2-propanol is presented as a method which significantly lowers the GC–MS detection level compared to other alcohol derivatization agents.     

裂隙岩体渗透系数确定方法研究

裂隙岩体渗透系数以及渗透主方向的确定对研究岩体渗透性大小及各向异性具有重要意义。高放废物地质处置库介质岩体的渗透性能将直接影响其使用安全性。本文运用离散裂隙网络模拟的方法对我国高放废物处置库甘肃北山预选区3#钻孔附近裂隙岩体进行了渗透性质分析。通过对3#钻孔1715～1780m段压水试验数据的反演,标定了离散裂隙网络渗流模型中的裂隙渗透参数(导水系数T)。利用标定的离散裂隙网络模型对场区裂隙岩体进行了渗流模拟,确定了该区域裂隙岩体的渗流表征单元体(REV)的尺寸大小以及渗透主值和主渗透方向。运用离散裂隙网络模型计算得出的渗透主值的几何均值与现场压水试验计算结果较接近,证明了计算结果的有效性。     

泰山经石峪缓坡石坪片状剥落风化的几何特征

针对异径管的冲蚀失效问题,以管壁腐蚀产物保护膜为研究对象,主要研究流固耦合对管道 冲蚀破坏的作用机理. 建立流固耦合数理模型,推导出在任意拉格朗日-欧拉(Arbitrary Lagrange-Euler, ALE)描述下的黏性流体N-S方程和腐蚀产物保护膜固体区域的控制方程, 分析管壁边界层多相流介质流动与腐蚀产物保护膜破损之间的耦合作用. 以异径管冲蚀失效 为例,运用多物理场耦合软件,分析了异径管流体流向、结构和规格对保护膜变形的影响, 模拟结果表明：流向为``大进小出'的冲蚀较严重;偏心异径管比同心异径管冲蚀严重;两 端管径差越大,冲蚀越严重. 可为异径管的失效分析、优化设计和在役检验提供参考.     

易贡滑坡堰塞湖溃坝洪水分析

滑坡堰塞坝体主要由块石、碎石土等松散材料组成,随着上游水位的不断上升,极易失稳,一旦决口将对给下游人民的生命财产安全造成极大的威胁。因此,研究堰塞坝溃坝问题具有重要的学术意义和应用价值。2000 年 4 月 9 日,西藏林芝地区波密县易贡藏布河扎木弄沟发生大规模山体滑坡堵塞易贡藏布江,形成坝高60m,长约2500m,库容可达288×108m3,体积约28×108～30×108m3的滑坡堰塞湖, 2000年6月10日堰塞坝溃决。本文以易贡堰塞湖溃坝为例,从连续性方程及Navier Stokes方程出发,结合标准型湍流模型,并采用VOF方法进行自由面处理,基于流体计算软件Fluent模拟分析了溃坝洪水在下游弯曲河道的演进过程及不同位置的流速变化。数值模拟结果与实测资料记录基本一致,表明该模型能够模拟溃坝洪水在地形复杂弯曲河道中的演进过程。     

Synthesis of the water-compatible p-acetaminophen resin and its adsorption performances for vanillin in aqueous solution

A novel p-acetaminophen resin(named as GQ-1) was synthesized with chloromethylated polystyrene and p-acetaminophen.It can be used without any wetting process.The objective of this work was to study the adsorption performances for vanillin onto GQ-1 with two kinds of the hydrogen bond site of acetamino group and hydroxyl group.The results showed that the adsorption property of vanillin onto GQ-1 was superior to XAD-4,H103,NDA150,and NDA88.The adsorption capacity of vanillin onto GQ-1 is not greatly discrepant until the solution pH is higher than 5.31.The saturated adsorption quantity of vanillin was up to 141.32 mg/mL(wet resin) according to the dynamic adsorption and desorption experiments at 293 K.The resin could be regenerated by 7 BV ethanol.     

世界三大典型水库型顺层岩质滑坡工程地质比较研究

通过对瓦依昂滑坡、塘岩光滑坡、千将坪滑坡滑坡三大滑坡工程地质比较研究,找出了其地形地质条件、诱发因素、变形特征的基本规律和共性,揭示了库水浮托与滑带浸泡软化及二者耦合的滑坡诱发机制; 提出了水库顺层岩质滑坡的基于易滑地质结构的空间预测模型; 初步总结了水库顺层岩质滑坡短期及临滑变形特征。     

一维光子晶体中亚波长缺陷膜对Goos-Hnchen位移的调制特性

      利用传输矩阵法分析一维光子晶体中亚波长缺陷膜对缺陷模频率处Goos-Hnchen位移的调制特性,讨论了亚波长缺陷膜的厚度、磁导率及介电常量对一维光子晶体缺陷模频率处的Goos-Hnchen位移的影响.研究发现：一层几何厚度极小的亚波长薄膜即可非常灵敏地调制一维光子晶体缺陷模频率处Goos-Hnchen位移的位置及其大小;并且当亚波长缺陷膜为左手材料时,Goos-Hnchen位移随亚波长缺陷膜物理参量的变化趋势与普通右手材料时的情形完全相反.     

西藏樟木口岸古滑坡变形监测分析

樟木口岸古滑坡位于喜马拉雅山脉南麓,地形陡峻,构造运动强烈,地震活动频繁,雨量丰沛,基底为前震旦系达莱玛桥组黑云斜长片麻岩、片岩,上覆第四系残坡积、崩坡积物。本文采取地表裂缝监测、地表位移监测和深部位移监测3种方法,对古滑坡的变形特征与规律进行了较系统研究分析。监测结果表明两个古滑坡未发生变形,处于稳定状态,福利院古滑坡体中部发生复活,即消防队次级滑坡,目前该滑坡处于蠕动挤压阶段,变形呈缓慢增长趋势,降雨和人为开挖坡体是滑坡复活的诱发因素。     

Spectroscopic studies of 5,5′-dimethoxy-3,3,′-disulfobutyl-9-ethylthiacarbocyanine (DDTC) in solutions and immobilized in sol-gel matrices

Absorption spectra of 5,5′-dimethoxy-3,3,′-disulfobutyl-9-ethylthiacarbocyanine (DDTC) in aqueous solutions and immobilized in xerogels prepared by the sol-gel method were obtained. Influence of pH, detergent (Triton X-100), ethanol addition and sol-gel preparation method on the dye aggregation equilibria and its photostability were investigated. In liquid solutions lowering of pH, as well as addition of the detergent, shift the aggregation equilibrium towards the DDTC monomeric form. However, while more acidic conditions result in a decrease of the dye stability, addition of the detergent has a slightly stabilizing effect on the dye. However, addition of ethanol drastically reduces the DDTC photodecomposition and shifts the aggregation equilibrium towards the dye monomer. Entrappment of the thiacarboxycyanine in sol-gel matrix does not prevent the bleaching although the entrapped dye displays significantly increased stability. Lowering of temperature and keeping the doped xerogels in the dark further retards the immobilized dye bleaching and dimer formation.     

数据库管理系统在地震滑坡研究中的应用——地震滑坡数据库管理系统

地震滑坡资料是深入研究地震滑坡问题的宝贵基础资料,但是目前对这些资料缺乏有效的管理和利用。本文介绍的地震滑坡数据库管理系统可以科学合理地对这些资料进行高效管理,节省科研前期的投入,提高工作效率。本系统界面友好、操作方便,具有良好的可维护性、可扩充性和升级换代能力,可以加速地震滑坡问题的研究步伐,是地震滑坡问题研究的一个有力工具。